I'm the Chrome browser security tech lead, so it might help if I explain our reasoning here. The only strong permission boundary for your password storage is the OS user account. So, Chrome uses whatever encrypted storage the system provides to keep your passwords safe for a locked account. Beyond that, however, we've found that boundaries within the OS user account just aren't reliable, and are mostly just theater.

Consider the case of someone malicious getting access to your account. Said bad guy can dump all your session cookies, grab your history, install malicious extension to intercept all your browsing activity, or install OS user account level monitoring software. My point is that once the bad guy got access to your account the game was lost, because there are just too many vectors for him to get what he wants.

We've also been repeatedly asked why we don't just support a master password or something similar, even if we don't believe it works. We've debated it over and over again, but the conclusion we always come to is that we don't want to provide users with a false sense of security, and encourage risky behavior. We want to be very clear that when you grant someone access to your OS user account, that they can get at everything. Because in effect, that's really what they get.